5. Protective measures necessary for toxic materials a. Operations in closed systems b, Good ventilation c. Protective clothing d. Good personal hygiene practices Pyrophoricity 1. Pyrophoric materials capable of igniting spontaneously 2. Uranium, plutonium, thorium, zirconium, sodium, and potassium are used in atomic energy industry 3. Spontaneous ignition of massive metal is very rare 4. Most severe pyrophoric problems arise when metal is in powder form a. Powders have much greater surface area on which to generate heat b. Powders have much smaller mass of metal in which to dissi pate this heat c. Powders have much smaller percentage of total surface area available for loss of heat to external surroundings 5. Moisture increases pyrophoricity a. Some metals react violently with water b. Uranium high termperature reaction with steam is much more violent than with oxygen ce. Only common factor involved in all pyrophoricity accidents investigated is hydrogen DO’ ARCHIVES

Select target paragraph3