RADIOCHEMICAL-DATA CORRELATIONS
ON DEBRIS FROM SILICATE BURSTS

GLENN R. CROCKER, FRANCIS K. KAWAHARA, and EDWARD C. FREILING
U. S. Naval Radiological Defense Laboratory, San Francisco, California

ABSTRACT
Local-fallout samples collected in 1962 in the Johnie Boy, Small Boy,

and Sedan shots were analyzed radiochemically for *Sr, *sr, *'y, zr,

9Mo, Ru, Ru, 7, pe, Mog Wicg MB, Mice Mice 2%Np and

?39pu. These results, as reported by the project officers, have been
correlated by plotting the log of the ratio of equivalent fissions of each

nuclide,

i,

to equivalent fissions of *Zr, Yr;95, against the log of the

similar ratio for ™Sr and *°Zr, roy 9¢. The data werefitted to straight

lines by linear regression; and slopes, intercepts, coefficients of correlation, and confidence limits were determined. The slope of such

a line for a nuclide i is an indication of the degree of fractionation of

the nuclide relative to the fractionation of *’Sr. For all cases observed
in these Nevada shots, the same groupof nuclides (®Sr, °°sr, *ty, *Ru,
Ru, MY, pe, B8Cg MOR, MICs Mice, and 78°Np) fractionated from
*°Z7r. The nuclides Mo, '“4Ce, and ***Pu did not fractionate appreciably
from ™Zr. For the Sedan shot the slope of the '’Cs plot is near 1.0,

but, for the remaining fractionating nuclides, the slopes lie within a
narrow intermediate range. For the Johnie Boy and Small Boy shots,
for which the results are quite similar, these slopes show much wider
variation. The results of the correlation have been compared with

those from similar correlations for a coral-surface burst and some

air bursts. Aside from the fact that °*Mo fractionated from *°Zr in the
air bursts and that ?Np did not fractionate from *°Zr in the coral-

surface burst, the results indicate that differences in the fractionation

behavior of the nuclides are of degree rather than of kind. Correlation
of radiochemical results with particle size indicates increasing degree
of fractionation with increasing particle size.

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