PARTICLE CHARGING AT LOW PRESSURES BENJAMIN Y. H. LIU and KENNETH T. WHITBY University of Minnesota, Minneapolis, Minnesota ABSTRACT The electric charge imparted to particles at reduced pressures has been measured for particles ranging from 0.02 to 2.0 u and for pres- sures ranging from 0.01 to 1.0 atm with an improved particle- mobility analyzer of cylindrical geometry. The solid spherical particles of methylene blue dye are charged by positive ions in electric fields of various intensities. The measured particle charge is generally higher than the values predicted by White’s equations, and the difference in- creases with decreasing pressure. Typically, the measured charge at 0.01 atm is 100% higher than the values predicted by the diffusion- charging equation and is slightly less than one order of magnitude higher than what the field-charging equation predicts. INTRODUCTION The electrical charging of small particles in the micron and Submicron size range has been the subject of numerous theoretical and experimental studies. It is an important factor in the design of elec- trostatic precipitators, which are among the most effective devices for removing small airborne particulate matter. Electrostatic precipitators have been used extenSively as air or gas filters and, more recently, as atmospheric dust samplers at both ground levels and high altitudes for radioactive-fallout studies. Particle-charging experiments have been reported by Hewitt,! Penney and Lynch,’ White,’ Cochet,* Drozin and La Mer,°* Langer,® and others, and considerable particle-charging data are now available for 260

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