Health Effeces of Chemical Toxicants and Effluents

Determination of Trace Metals

in Human Tissues and

Project Title: Their Influence on Certain Diseases
Publications:
13.

RX-01-04

Preject not yet initiated.
14.

Scope:
A) 200 Word Summary:
The generation of power by fossil fuels results in the release of not

only vast amounts of carcinogenic hydrocarbons and oxides of nitrogen and

sulfur but also trace metals dependent upon the origin of the coal or oil.
The effluent industrial gases and liquid wastes introduce large amounts of
a wide spectrum of metals, many of which may be toxic and some of which have
been shown to be toxic in relatively small concentrations

(arsenic, beryllium,

titanium, fluorine, cadmium, barium, mercury, lead, vanadium, and bismuth).

These elements are alien to the body and can cause various kinds of chronic
degenerative conditions.
Neither the degree of exposure nor the manner in
waich the human body must become exposed for disease to develop are understood.
The concentration of these materials in human tissues and food has
not yet been adequately investigated.
This study proposes to determine the
concentration of these materials in human tissue obtained from individuals

at all stages of life and in addition to begin studies of amnionic fluid,
cord blood, fingernail and hair from live newborns and all tissues from
stillborns. With the development of highly inbred strains of rats with

innate dispositions to develop hypertension or to be resistant to hypertension,
and hypercholesterolemia and ultimately atherosclerosis it is possible to
,
critically evaluate the role that is played by cadmitm or vanadium in the

development of hypertension and atherosclerosis.
B)

Supplement to 200 Word Summary:

Elements which are either normal constituents of tissue or essential to

life may cause disease either by being scarce or in excess.

are:

chromium, manganese,

iron, nickel,

Such elements

copper, zinc, and selenium.

The

concentration of these elements will be studied in tissue samples originating
from human beings:
displaying symptoms which are similar to those induced
in animals by virtue of either excess or deficiency of the elements mentioned;
of residents of areas in which industrial and agricultural conditions are such
that one can easily suspect gross excesses or marked deficiency in a representative human population.
The nutritional and toxicological work involving
these metals in experimental animals is sufficiently extensive to permit
lection of human populations for sampling.

“technology that exists at Brookhaven for the study of metals is
rvé.
Chemical techniques and neutron activation analysis would be

helpful in specific instances but inadequate for population surveys.
X-ray
fluorescence is capable of determining, simultaneously, all elements of

atomic numbers greater than 15 present in sub-nanogram amounts of tissue.

RARAF is

ideally suited for the excitation of the characteristic x-ray

fluorescence and with on-line computer analysis assays are quick and

economical.

(See Continuation Sheet)

RX -96

ny

b119253

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