ee Boe at ae

oO

POLARIZATION

ABSORBANCE (RELATIVE)

18]

|

290

i

300

J

]

320

340

j

360

|.

380

j

=6400

0

WAVELENGTH (mj)

Fic. 139.-—-Absorbance of 1,3,6,8-tetrapheny] pyrene and corresponding polarization of emission

tion at the long-wavelength end of the range is that
of the grating, 410 mp.
SEARCH FOR HIDDEN LEVELS

Several additional compounds have been studied;

also, some of those studied previously have been re-

studied for more complete information. As pointed
out previously, in general it has been found not
worth while to study a compound in a liquid medium

unless the compound has a very short fluorescence

decay time of the order of one nanosecond) because

otherwise depolarization reduces the values to the

point where trends are obscured. Table 66 gives the
additional results to date. The long-wavelength edge
of the first absorption band is given to provide orien-

tation for the reader. Also, to aid in the visualization
of the results, curves are given in Figure 139 of absorption and corresponding polarization of emission

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