. ' . 5 Gece cael ahead Ls ilaeanea Ryedale abe. 139 \ oO 1000 + °5 NS > ._ = O----- 5 Oo O < Zz ° oO LABORATORY Oo N 8 9° orm | — 3000 } q> \ N\ = ; 0 \ _ —_z¥ o 0.10 0.20 0.40 12 14 16 18 500 ° \ SO, CONCENTRATION, ppm 1000 = ~+{ \ 0 5 2000 — 1500 = sneone . e Oo =° —— 200 3900 | \ oO — 4000 —{ 2500 - ? ° Q 5 °ol- — SCRUBBER IN 400 NATIONAL O \ 3 w 600 x STATION: ARGONNE ° IN o CST __!00 Time ‘N\A O o> ~~~ SCRUBBER IN E . o c a2 pate [6 APRIL 1969 \ 1200 — 4500 | | N\ “ee 20 22 AIR TEMPERATURE, °C Fre. 101.—Vertical SQ, and temperature profiles, Argonne National Laboratory, April 16, 1969, 1100 CST seemed to the observer in the aircraft to originate in the Ridgeland Power Station and the Chicago Sani- tary District Plant in Stickney. This airport is about 10 miles from these sources. The SOz and temperature profiles at this airport are shown in Figure 99. A dry adiabatic lapse rate 2000 ft thick was observed just below a weak inversion. The SO. data show that SO. levels were high and rather uniformly mixed in this layer, with a very rapid decrease to background levels above the base of the inversion. This figure rather convincingly demonstrates the importance of the mixing layer concept and how even a weak inversion aloft can act as a lid to dispersion and vertical mixing. The temperature profiles at Midway and Argonne were quite similar to that of Figure 99; SO. concentrations below the inversion were considerably lower than those observed at Hinsdale Airport. The sound- ings at Meigs show near zero SOzat all heights, with a cool surface layer caused by on-shore winds. Oneleg of the return flight was going north at con- stant levels (980 ft, MSL) along County Line Road from 95th Street (Des Plaines River) to Cermak Road (2200 South). (County Line Road runs N-S along the boundary between Cook and DuPage Counties.) The SOz recorder trace for this leg is shown in Figure 100. SOs levels were quite high (0.25 to 0.33 ppm) in the visible plume, much lower on either side. The figure shows that valuable pollution information can be gained on horizontal as well as vertical flights. The ragged nature of the interesting SO2 cross section may be due to incomplete horizontal mixing from several large point sources. A simple diffusion calcula- tion, using typical SO2 outputs from the two plants mentioned above, the Gifford™) diffusion parameters, and the observed weather information, shows that most of the observed SOs concentration at Hinsdale Airport could have originated at these two sources. Not too much should be inferred from this calculation, as the real SO» emission rates were not known and the SO, contributions from all the other possible sources were ignored. Figure 101 shows the SO. and temperature profiles at Argonne on April 16, 1969 at 1100 CST. South winds at 8 mph with clear skies were present when the sounding was made. The temperature data show the expected adiabatic layer with a weak (~1° C) inversion at 2000 ft. Even this inversion was enough to ta near the center of the visible smoke plume moving to the SSW along the Expressway. Most of the plume gh