135
asked to convert to maximum use of high-sulfur coal

or oil. During this week, industry was asked to recon-

vert to minimum-sulfur fuels on a date selected on

the basis of the weather forecast, with the Edison
Company following one day later. Fortunately, the
weather did cooperate this week.
When the city converted to maximum use of high-

sulfur fuels on July Ist, four of the eight TAI stations reported rapid and large increases in SQ. values
(from 0.00 to 0.23 ppm in 15 min at one site, for ex-

ample). Fluctuations during the balance of the day
can be related to changes of wind direction. Very low
ground-level SOs concentrations were often observed
at night and early morning during the high SO2 output period with light winds and strong, ground-level

inversions, showing that the pollutants were trapped
above the stable layer and did not reach the surface.

On July 3rd, when a lake breeze circulation covered
the city, a SO. concentration of 0.47 ppm was observed at one station, This occurred several hours af-

ter the lake breeze front passed the station, showing
that the SO. was trapped in the relatively cool, stable

air moving in from the lake. No high SOs levels were
observed at any station in the zone of convergence
along the lake breeze front.

The data show that sources outside of the city are

often responsible for high SOs levels inside the city.
The third fuel-switch test in this serics was con-

ducted between May 19th and May 30th, 1969. Dur-

ing this experiment, the dual-fueled plants and the
electrical generating plants were asked to convert to
hich sulfur fuels on May 20th and May 26th. The conversions to low sulfur fuels were made one or two days
later using a selective abatement strategcy; that is,
only a limited numberof plants changed to low-sulfur
fuels. The abatement strategy used depended on the
actual and forecast weather conditions, observed and

forecast SO» levels, location of dual-fuel plants with

respeet to the SO. observing sites, diffusion calculations, and the availability of natural gas. Only those
sourees contributing to areas of high SO. concentrations were asked to convert to gas. The strategy emploved in this test is quite similar to that which
would be used during a real air pollution episode. The
observed changes in SOs levels indicated that fuelswitches were effective in lowermg SOQ-s concentrations
in the affeeted areas, and that the decreases were con-

sistent with those computed bythe diffusion model. A

complete analysis of this experiment in pollution
abatement is in progress,

CHICAGO AIRCRAFT SOUNDING PROGRAM
J.E. Carson and D. MM. Nelson
Atmospheric stability, as measured by the vertical tempera-

ture distribution. is an important meteorological factor controlling diffusion rates. Until recently, no measurements of this
parameter were being made in or near Chicago. The Chicago
Department of Air Pollution Control has purchased a flight
package to measure vertical profiles of air temperature and
sulfur dioxide. Both helicopters and light airplanes have been
used; Argonne and city scientists have made flights with the

svstem. About fifteen flights were made during the period of
this report; features of several of the more interesting flights
are presented,

Until recently, two types of meteorological measurements needed to accurately estimate diffusion conditions over Chicago were not being made. These are

the vertical temperature gradient and winds in the
zone of mixing and transport. The vertical temperature gradient (lapse rate) determines the atmospheric

stability and (combined with wind speed and surface -

roughness} the intensity and spectrum of turbulence.

The depth of the mixing layer (thatis, the volume of
air in which the pollutants can be mixed) is determined by the height above ground and intensity of
stable layers (inversions) aloft; it is very difficult if

not impossible to estimate this critical pollution parameter without direet measurements.

The low-level lapse rate varies with time and height

as well as horizontally in an urban area such as Chicago with its mixture of tall and low buildings, roads,

parks, lake, ete. In dispersion calculations, the lapse

rate in the first several hundred feet above ground is
usually estimated from standard weather observations
(wind speed, cloud cover, time of day, etc.) using ob-

jective techniques, such as those proposed by Gifford™ and Pasquill.@ Unfortunately, these procedures cannot be used to provide accurate estimates of
the mixing depth.
Techniques to extrapolate the observations from the
two nearest U. 8. Weather Bureau radiosonde stations
(Peoria, Illinois, 140 miles southwest of the Loop and
Green Bay, Wisconsin, 180 miles north) have been
developed at Argonne and bya local private meteorological forecasting service (Sce Reference 3, p. 129).
These procedures cannot be expected to be sufficiently
accurate or detailed always to represent conditions
over Chicago.

Select target paragraph3