1 CRER-1068 INTRODUCTION Natural strontium and barium are invariably present in plant and animal tissue and in surface waters, but the concentrations of these elements are several orders of magnitude lower than those of calcium and magnesium. Nevertheless, the amounts are sufficiently high to affect the chemical yield in the estimation of strontium-90 by carrier methods. This error can be minimized by increasing the weight of carrier substantially, by using : strontium-85 for the estimation of yield, or by determining the natural strontium present in the sample and correcting thecarrier weight accordingly. Frequently, it is sufficient to establish that the natural strontium/calcium ratio in a particular type of material is relatively low and hence introduces, at most, a small error. In addition to the requirement for analytical purposes, \ results can be used in an alternate manner. estimation of ‘discrimination factors! They allow the for strontium in the food chain, or alternatively, if radiochemical data are available, the pecific activity of strontium (strontium-90/natural strontium) y be calculated for particular food chains. This may sometimes be preferable as it avoids the concept of ‘discrimination factor! lor 'observed ratio', This report outlines procedures for the estimation of natural strontium, barium and calcium and presents results of the determination of these elements in the: above mentioned matertals. pond Strontium and barium were determined by activation oy analysis. Both elements form short-lived radioactive isotopes,

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