from zirconium by precipitation as fluorides.

Cerium wes sep-

arated from trivalent rare earths by precipitation as ceric
fodate.

In analysis of Rojoa dredged sand an attempt was made

to separate trivalent rare earths from yttrium by precipitating them on lanthanum carbonate, but absorption curve study
showed that this separation was not complete.

A large fraction

of other trivalent rare earth isotopes had carried on yttrium

instead of on lanthanum.

The two results were added together

and reported as trivalent rare earths.

This separation was not

attempted in other analyses.

Trivalent rare earths were counted

together on yttrium carrier.

The rare earths were weighed as

oxalates.

Zirconium was recovered from the flouride supernate

by precipitation first as barium fluozirconate and than as

zirconium mandelate, which was ignited and weighed as zirconfum oxide.

The supernate from the hydroxide precipitation

contained barium, strontium,

as carbonates.

and calcium which were precipitated

Barium was separated as barium chromate and

strontium and calcium precipitated together as oxalates.

Chem-

ical separation of strontium and calcium was not attempted.

A

separate aliquot of Rojoa dredged sand solution was analyzed
for cesium by the standard cesium perchlorate method and no de-

tectable radiocesium was found.

Since rubidium also is carried

on this precipitate it is evident that rubidium was also absent.
In most samples the absence of cesium was

indicated by the ab-

sence of activity in the solution remaining after precipitation
of rare earth hydroxides and alkaline earth carbonates.
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81

Ruth-

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parr ARCH res

GT

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