Stress increases pyrophoricity a, Stress can be physical or chemical b. Uranium lathe chips more susceptible to spontaneous igni- tion than annealed metals of same dimensions in sheet form Ruptured fuel elements in a nuclear reactor present a very real fire hazard a. Chalk River incident b. Windscale reactor incident With fissionable materials, fires are limited by criticality considerations Methods used to handle pyrophoric materials a. Finer the material the smaller the quantities handled b. Layers of pyrophoric material are kept thin ce. Initial surface treatment (slow exposure of pyrophoric materials to dry oxygen) 10. d. Keeping pyrophoric materials under an inert atmosphere e. Fires fought with graphite powders Serious pyrophoric incidents that have occurred and corrective measures taken a. .b. ce. Y-12 area (1956) Uranium rolling operation (1956) Sylvania plant (1956) DOS ARCHIVES

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