FISSION PRODUCTS IN THE ATMOSPHERE AND IN RAIN P, K. KURODA, PENTTI KAURANEN,* B. D. PALMER, K, K. MENON, and L. M. FRY University of Arkansas, Fayetteville, Arkansas ABSTRACT The concentrations of sr, sr, “°Ba, ‘!ce, and ‘Ce in individual samples of rain and snow have been measured radiochemically at Fayetteville, Ark., for the past several years. Certain features of the isotopic ratio data may be explained as being due to atmospheric fractionation of nuclear debris taking place on a global scale. High con- centrations of Mn, '*4Sb, and '°Sb were observed in the air-filter samples collected in connection with Project Star Dust in 1962 and 1963. The '5sp/®sr ratio in 1963 samples was found to correspondto values reported for the production ratio in thermonuclear explosions, but some samples collected at high northern altitudes in 1962 showed an excess of ‘Sb. It appears that 25Sbh was partly produced through second-order neutron capture in '%sgb. A sudden increase of “Mn con- centration was observed in April 1963 at an altitude range of 30,000 to 35,000 ft. INTRODUCTION Levels of sr, Sr, “Ba, ‘Ce, and '“4Ce in individual samples of rain and snow have been measured radiochemically at Fayetteville, Ark., during the past several years. A set of Project Star Dust high- altitude air-filter samples was received by the University of Arkansas in the fall of 1963, and a study on the distribution of fission products and a number of nonfissiogenic nuclides such as *4Mn and '4Sb has recently been undertaken. | *Present address: Department of Physics, University of Helsinki, Helsinki, Finland. 602

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